Mysterio (The Spectacular Spider-Man)

Quentin Beck was a film special effects expert and stuntman. At some point later, Beck had been part of the Chameleon's crew alongside Phineas Mason aka the Tinkerer. The Chameleon impersonated Spider Man using Beck's special effects technology, framed him whilst on a crime spree. The group were then taken down by the real Spider-Man with the help of the Black Cat.[1]

Quentin Beck later returned with a new identity of Mysterio and stole technology from Tricorp and Oscorp, whilst pretending to be a sorcerer "saving" mankind from the evils of technology.