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as Leonard Nimoy
Episodes: Marge vs. the Monorail (Season 4, Episode 12)
The Springfield Files (Season 8, Episode 10)
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as Hank Scorpio
Episode: You Only Move Twice (Season 8, Episode 2)
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as Leon Kompowsky
Episode: Stark Raving Dad (Season 3, Episode 1)
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as Coyote
Episode: El Viaje Misterioso de Nuestro Homer (Season 8, Episode 9)
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as Chester J. Lampwick
Episode: The Day the Violence Died (Season 7, Episode 18)
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as John
Episode: Homer's Phobia (Season 8, Episode 15)
as Mark Hamill
Episode: Mayored to the Mob (Season 10, Episode 9)
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as Ron Howard
Episodes: When You Dish Upon a Star (Season 10, Episode 5)
Hello Gutter, Hello Fadder (Season 11, Episode 6)
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as The Ramones
Episode: Rosebud (Season 5, Episode 4)
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as Stephen Hawking
Episodes: They Saved Lisa's Brain (Season 10, Episode 22)
Don't Fear the Roofer (Season 16, Episode 16)
Stop or My Dog Will Shoot (Season 18, Episode 20)
Elementary School Musical (Season 22, Episode 1)
as Adam West
Episodes: Mr. Plow (Season 4, Episode 9)
Large Marge (Season 14, Episode 4)
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as Stan Lee
Episode: I Am Furious Yellow (Season 13, Episode 18)
as Gary Coleman
Episodes: Grift of the Magi (Season 11, Episode 9)
A Tale of Two Springfields (Season 12, Episode 2)
as James Woods
Episode: Homer and Apu (Season 5, Episode 13)
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as Sting
Episode: Radio Bart (Season 3, Episode 13)
as Alan Moore
Episode: Husbands and Knives (Season 19, Episode 7)
6.8
17. U2
as U2
Episode: Trash of the Titans (Season 9, Episode 22)
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as Tom Hanks
The Simpsons Movie
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as Cecil Terwilliger
Episodes: Brother from Another Series (Season 8, Episode 16)
Funeral for a Fiend (Season 19, Episode 8)
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as Herb Powell
Episodes: Oh Brother, Where Art Thou? (Season 2, Episode 15)
Brother, Can You Spare Two Dimes? (Season 3, Episode 24)
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and Bret McKenzie as Ethan and Kurt
Episode: Elementary School Musical (Season 22, Episode 1)
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as Mel Gibson
Episode: Beyond Blunderdome (Season 11, Episode 1)
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as Tito Puente
Episode: Who Shot Mr. Burns?: Part 1 (Season 6, Episode 25)
Who Shot Mr. Burns?: Part 2 (Season 7, Episode 1)
as Dennis Franz playing Homer Simpsons
Episode: Homer Badman (Season 6, Episode 9)
as The Who
Episode: A Tale of Two Springfields (Season 12, Episode 2)
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as Maggie Simpsons
Episode: Treehouse of Horror V (Season 6, Episode 6)
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as James Taylor
Episode: Deep Space Homer (Season 5, Episode 15)
as Pierce Brosnan house
Episode: Treehouse of Horror XII (Season 13, Episode 1)
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as Number One
Episode: Homer the Great (Season 6, Episode 12)
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as Mickey Rooney
Episode: Radioactive Man (Season 7, Episode 2)
as Barry White
Episodes: Whacking Day (Season 4, Episode 20)
Krusty Gets Kancelled (Season 4, Episode 22)
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as Lyle McCarthy
Episode: Homer the Whopper (Season 21, Episode 1)
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as Fox Mulder and Gillian Anderson as Dana Scully
Episode: The Springfield Files (Season 8, Episode 10)
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as Donny
Episode: The DeBarted (Season 19, Episode 13)
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as Neil Patrick Harris playing Bart Simpson.
Episode: Bart the Murderer (Season 3, Episode 4)
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as Conan O'Brien
Episode: Bart Gets Famous (Season 5, Episode 12)
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as Mindy Simmons
Episode: The Last Temptation of Homer (Season 5, Episode 9)
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as Laura Powers
Episode: New Kid on the Block (Season 4, Episode 8)
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Ted Danson, Woody Harrelson, Rhea Perlman and John Ratzenberger as the cast of Cheers.
Episode: Fear of Flying (Season 6, Episode 11)
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as Ray Patterson
Episode: Trash of the Titans (Season 9, Episode 22)
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as Stephen King
Episode: Insane Clown Poppy (Season 12, Episode 3)
as Betty White
Episodes: Missionary: Impossible (Season 11, Episode 15)
Homerazzi (Season 18, Episode 16)
as Paul McCartney
Episode: Lisa the Vegetarian (Season 7, Episode 5)
Wade Boggs, Jose Canseco, Roger Clemens, Don Mattingly, Steve Sax and Mike Scioscia as Themselves.
Episode: Homer at the Bat (Season 3, Episode 17)
as Lucy Lawless
Episode: Treehouse of Horror X (Season 11, Episode 4)
as Jim Jarmusch
Episode: Any Given Sundance (Season 19, Episode 18)
as Richard Dean Anderson
Episode: Kiss Kiss, Bang Bangalore (Season 17, Episode 17)
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as R.E.M.
Episode: Homer the Moe (Season 13, Episode 3)
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as Ernest Borgnine
Episode: Boy Scoutz 'n the Hood (Season 5, Episode 8)
as Bob Newhart
Episode: Bart the Fink (Season 7, Episode 15)
With 23 seasons and over 500 episodes so far there has been a lot of great guest stars on this show. I know i must have missed a few great ones, so please tell me is there is a great guest appearance that should have been on the list.
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